Phase Transitions in Colloidal Suspensions

Book excerpt: The first five articles in this issue emphasize equilibrium phases and structures. The hard sphere properties of sterically stabilized particle suspensions are examined in the article by van Megan, Pusey and Bartlett, a colloidal compound is discussed by Hachisu and attractive interactions are shown to produce a full complement of phase transitions including a liquid/gas transition by Emmett and Vincent. Recent theoretical interest in the nature of melting in two dimensions has led to the investigation of the melting transition in colloidal systems where the particles are constrained to a single layer. Murray, Van Winkle and Wenk present experimental results supporting the view that two dimensional melting is mediated by two second order transitions, while Tang, Armstrong, Mockler and O'Sullivan present results suggesting a first order process in a similar colloidal monolayer.